Sodium diffusion in alkali feldspars

Autor(en)
Bengü Tas, Alexander Gorfer, Elena Petrishcheva, Gerhard Wilde, Rainer Abart, Sergiy Divinski
Abstrakt

Tracer diffusion of Na in natural alkali feldspars including sanidine, adularia and orthoclase with different Na:K ratios, minor element contents and different degrees of Al/Si ordering is investigated using the radiotracer technique employing (Formula presented.) Na as the radioisotope. In adularia, the tracer diffusion measurements along the crystallographic directions ⊥(001) and ⊥(010) revealed a slight (within a factor of two to three) anisotropy of Na diffusion, with the faster diffusion rates along the ⊥(001) direction. The full diffusivity tensor for Na diffusion in one orthoclase is determined and a strong, temperature-dependent anisotropy of diffusion in the (010) plane is found. The state of Al/Si ordering is inferred to have a significant influence on the Na diffusion rates in alkali feldspar, while the presence of spurious alkaline impurities and major element composition plays a less important role.

Organisation(en)
Department für Lithosphärenforschung, Isotopenphysik
Externe Organisation(en)
Universität Münster
Journal
Philosophical Magazine
Band
105
Seiten
1606-1621
Anzahl der Seiten
16
ISSN
1478-6435
DOI
https://doi.org/10.1080/14786435.2025.2531527
Publikationsdatum
2025
Peer-reviewed
Ja
ÖFOS 2012
105120 Petrologie
Schlagwörter
ASJC Scopus Sachgebiete
Condensed Matter Physics
Link zum Portal
https://ucrisportal.univie.ac.at/de/publications/0c87f8b2-aad8-44e2-a063-75337ff602c5